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Carbon Dioxide CO2 Exposure Limits & Toxicity to humans: this document discusses normal and abnormal CO2 gas levels, the toxicity and exposure limits for exposure to carbon dioxide gas (CO2). We discuss Carbon Dioxide gas levels in outdoor air, in buildings, typical CO2 levels and conditions under which levels are unsafe. We discuss the symptoms of carbon dioxide poisoning, describe different types of risks where high levels of CO2 may be present, and present data about the effects of CO2 exposure. Seek prompt advice from your doctor or health/safety experts if you have any reason to be concerned about exposure to toxic gases. Links on this page also direct the reader to carbon monoxide gas information in a separate document. We give references and explanation regarding toxicity of Carbon Dioxide.
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Symptoms of high or prolonged exposure to carbon dioxide include headache, increased heart rate, dizziness, fatigue, rapid breathing, visual and hearing dysfunctions. Exposure to higher levels may cause unconsciousness or death within minutes of exposure.
What may be unclear in some cases is whether the sub-acute (sub-toxic) effects at modestly-elevated levels of CO2 in air stem from more from exposure to higher levels of carbon dioxide or whether they are due to reduced levels of oxygen. In an enclosed space such as a tight home or an enclosed basement or work space, increasing the level of CO2 is likely to simultaneously reduce the proportion of Oxygen (O2) in that same breathing air.
Some experts opine that complaints that seem to be associated with high CO2 problem in many if not most circumstances are likely to be actually due to the corresponding reduction in available oxygen in air rather than high toxicity levels of CO2 in the air. As carbon dioxide levels climb above a few percent the relative proportions of gases making up that air change: the concentration of oxygen in the air inhaled is reduced as the amount of CO2 is increased.
However, the TOXIC effects of elevated levels of CO2 are serious at levels when the oxygen reduction effects are only minor. 
IF YOU SUSPECT ANY BUILDING GAS-RELATED POISONING GO INTO FRESH AIR IMMEDIATELY and get others out of the building, then call your fire department or emergency services for help.
Here we discuss Carbon Dioxide gas levels in outdoor air, in buildings, typical CO2 levels and conditions under which levels are unsafe. We discuss the symptoms of carbon dioxide poisoning, describe different types of risks where high levels of CO2 may be present, and present data about the effects of CO2 exposure. Seek prompt advice from your doctor or health/safety experts if you have any reason to be concerned about exposure to toxic gases. Links on this page also direct the reader to carbon monoxide gas information in a separate document.
- Daniel Friedman, with special thanks to Per Levéen, Telia Mobile, Sweden , Dr. Roy Jensen, (Canada) . and Stephen Fisher, B.Sc., Sales Director, K.D.Fisher & Company, Pty., Ltd., Australia,  for technical editing & comments.
Per Levéen has thoughtfully provided the detailed analysis comparing the hazards of elevated carbon dioxide in a building with the accompanying reduction of oxygen (O2 ) in the same space if the percentage of CO2 is increased from a leak from a CO2 gas cylinder.  The data following has been modified by Stephen Fisher, B.Sc, Dip. Ed., Sales Director of K.D.Fisher & Co., Pty. Ltd.
FACT: 100 liters of air contains:
Preliminary Assumptions: If the 100 litres is contained in a balloon like membrane, then 1.4 litres of gas can be added, at the same pressure. If we add 1.4 litres of CO2 to this mixture, we will get 101.4 litres of air which has an elevated CO2 content, and a reduced oxygen content, see the calculation immediately below:
Carbon Dioxide: (1.4 + 0.04) / 101.4 = 0.014 = 1.42 % CO2 by bolume in air
This is is an increase in CO2 percentage of 35.5 times above the “normal level” of 0.04% CO2 by volume in air. 1.42% CO2 can also be expressed as 14,000ppm (parts per million) CO2.
Oxygen: 20.9 / 101.4 = 0.206 = 20.6 % oxygen.
This is a reduction in the oxygen percentage of 0.3% by volume in air, below the “normal” 20.9% Oxygen by volume in air.
This change in the mix of gases in air when the level of CO2 increased results in a decrease with 1.4% in the oxygen level (and not 6.7% as was stated at Example of Reduced Oxygen Level in a Building)
However, KC Baczewski PE writes that the above calculation should be
Case Report Example of Fatal Levels of Carbon Dioxide (CO2) in a Building
This is important because we recently had an accident with CO2 in Sweden killing two persons.
According to the newspapers CO2 is nontoxic and it is the decreased oxygen levels that kills. THIS CONCEPT IS WRONG.
Using the calculation equation above one can quickly conclude that adding 31 litres of CO2 to a 100 litre enclosed space would result in a 23.7% CO2 by volume in air, which would be almost instantly fatal, and 16% oxygen by volume in air, (equivalent to breathing at 2800 meters above sea level, which is dangerous, because it can lead to poor decision making, but not fatal).
In conclusion, in the event of a CO2 Cylinder leak, it is the toxic properties of CO2 that is fatal, long before oxygen levels have been reduced to fatally low levels.
According to the calculation shown below at Example of Reduced Oxygen Level in a Building, a level of 1.4% CO2 cause a drop of oxygen from 20.9% to 19.5%. As the arithmetic above shows, This calculation is misleading. Saying that adding 1.4% CO2 causes oxygen to drop to 20.9 - 1.4 = 19.5% is like saying that adding 20.9% CO2 would cause oxygen to drop to 20.9 - 20.9 = 0% That is of course not true. The correct and more precise calculation is provided above this paragraph.
Using either of the above calculation methods, the introduction of 5% CO2 to the room's air volume will reduce each of the components of normal air to 95% of their original proportion.
According to Example of Fatal levels of CO2 Carbon Dioxide in a Building (above), the math of the following example is not quite correct. We have kept Dr. Jensen's comments (below) but they should be read together with the detailed example and calculation provided above by Per Levéen.
More carbon dioxide may mean less oxygen: Let's say, sake of simplicity, that we're converting oxygen to carbon dioxide in an enclosed space. Then when the CO2 level has increased from its normal amount in air (about 0.03%) up to a higher concentration in air of 1.4% CO2 the concentration of oxygen in air will have decreased from 20.9 to 19.5%. Reducing the oxygen concentration from 20.9% down to 19.5% is equal to a 6.7% reduction in the oxygen level. -- Thanks to thanks to Dr. Roy Jensen for assistance with these details.
What are the effects on humans (and other animals) of reduction of the oxygen levels in air? At sea level, breathing air in which the O2 level has fallen to 16% percent is equivalent to being at the top of a 9,200-foot mountain - close to the level at which many people will experience shortness of breath while walking. 12% Oxygen in air at sea level corresponds to breathing normal air at an elevation of about 17,400 feet.
Original content, since extensively edited and expanded by several experts, began in 1985 with a literature search & search on Compuserve's Safety Forum by Dan Friedman. This is background information, obtained from expert sources. This text may assist readers in understanding these topics. However information presented here is not authoritative and may be incomplete.
Frequently Asked Questions (FAQs) about the toxicity of CO2 Carbon Dioxide Gas at various percentage concentrations or exposure levels
Question: progression of CO2 in the body at high levels
progression of high Carbon Dioxide in your body when it is 2% over the normal? / at what level do you do to STOP the the progression when it is 2% - E. Avery 7/23/2011
Question: where to place equipment to measure CO2 from a generator?
what is the distance i can plce the equipment in other to measure accurate reading of c02 emissions from a generator. - Afolabi 12/19/2011
The sensitivity and design-operating range of different types of gas detection equipment vary widely.
For example a ceiling mounted home carbon monoxide detector is intended to be placed at a variety of locations in a home, some many rooms away from the most likely CO source. But other test equipment may require distances ranging from centimeters to many meters. Our TIF 8800, for example, has a sensitivity adjustment. So without consulting the equipment instructions, there is no right answer to your question. And you scare us - let's hope no one's safety is relying on your approach.
Question: What is the math around PELS?
This article is interesting. I think I understand the concept but I have an application that use an analyzer.
- Syl 4/4/2-12
Syl, your question was a bit unclear and makes me worry that you are messing with gases without proper education or preparation. You are asking about Sulphur dioxide (SO2) in an article about Carbon dioxide (CO2) - in any event, if you are asking about recommended exposure limits for Sulphur dioxide SO2,
Dan, I can assure you that nobody will be put in danger. Proper assessment will be done by qualified people for installation certification. Let me reformulate my question. I am interested to know how we determine if an area could be potentially dangerous or not. I mentioned SO2 but we can do it with CO2 if you like. The math behind is what I am looking for. Let's say for instance that a 5m3 gas cylinder containing 2000 ppm of CO2 is totally released in a 1000m3 closed room. What would be the indication of a gas detector located in the room, assuming the gas occupy the whole area due to an internal air movement (I understand that some area can have a higher concentration than other depending of the gas properties). I don’t think that a meter would read 1000ppm of CO2 because it is diluted in the air. What would be the reading in the middle of the room?
Question: are there carbon dioxide hazards in the Space Station?
Why the health problems in space station reported by NASA long ago---at 500 ppm CO2? - Ron Schmoller 8/5/2012
Ron, if you can give us a citation, article, document source I'd be glad to take a look. A Google Scholar search for "Carbon dioxide hazards in the space station" didn't return a single article that addressed your question.
Question: question about CO Carbon Monoxide ... let's not confuse CO with CO2
can a person whose had serious exposure to carbon monoxide still be experiencing some symptons such as memory lost and irrasionality 2-3 years after their exposure? - (Aug 11, 2012) firstname.lastname@example.org
Question: will people in a car suffocate from CO2
Wonder if two people staying in a sedan car (sealed windows, no AC) will be suffocated of C02 in 30 minutes? - Atoi 9/10/2012
Atoi I think you are confusing CO (carbon monoxide) with CO2 (carbon dioxide) - or perhaps you are postulating that the automobile is airtight and that people are going to exhaust the available oxygen or suffer from high CO2 levels. In our experience, vehicles are not air tight, and the hazards arise from carbon monoxide from an idling engine or an exhaust leak, though I would agree that people breathing in an enclosed space will indeed push the CO2 numbers up.
Take a look at TYPICAL CO2 LEVELS - separate article for some examples of indoor or enclosed space carbon dioxide levels.
What is the mechanism of action in cases of carbon dioxide poisoning, assuming that the organism is provided adequate oxygen, that is, it does not suffocate? - H Durden 10/8/2012
The question you pose, along with both high CO2 effects and reduced oxygen efffects, is discussed in the article above.
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